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Watch Now. The show airs on Sunday nights, on the CBS network, at 10 p. CT, but week two of the new season will air at a different time. Tea Leoni maintains her record of having appeared in every episode of Madam secretary in season five. Elizabeth turned to former secretaries of state, Madeleine Albright, Hillary Clinton, and Colin Powell to attempt to keep the peace. Add to Favorites to get notifications right now! This device does not support web-push notifications. Alerts will be sent to your email:.
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